Functionalization of saturated hydrocarbons. 14. Further studies on the mechanism of Gif-type systems
…, F Halley, N Ozbalik, M Schmitt, E Young…
Index: Barton, Derek H. R.; Halley, Frank; Ozbalik, Nubar; Schmitt, Martine; Young, Esme; Balavoine, Gilbert Journal of the American Chemical Society, 1989 , vol. 111, # 18 p. 7144 - 7149
Full Text: HTML
Citation Number: 101
Abstract
Abstract: The photolysis (W light) of acyl derivatives of N-hydroxy-2-thiopyridone in pyridine- acetic acid permits a study of the partitioning of secondary radicals between oxygen, pyridine, and the thione function. Comparison with the GiPv oxidation system for saturated hydrocarbons confirms that radicals are not involved in oxidation at secondary positions. On the contrary, radical behavior at the tertiary position in adamantane is again established. ...
Related Articles:
[Czaplik, Waldemar Maximilian; Mayer, Matthias; Von Wangelin, Axel Jacobi Angewandte Chemie - International Edition, 2009 , vol. 48, # 3 p. 607 - 610]
[Czaplik, Waldemar Maximilian; Mayer, Matthias; Von Wangelin, Axel Jacobi Angewandte Chemie - International Edition, 2009 , vol. 48, # 3 p. 607 - 610]
[Minisci, Francesco; Fontana, Francesca Tetrahedron Letters, 1994 , vol. 35, # 9 p. 1427 - 1430]
[Minisci, Francesco; Fontana, Francesca Tetrahedron Letters, 1994 , vol. 35, # 9 p. 1427 - 1430]
[Yu, Tingting; Wang, Jiaqing; Li, Xinming; Cao, Xueqin; Gu, Hongwei ChemCatChem, 2013 , vol. 5, # 10 p. 2852 - 2855]