Reaction of stabilized bismuthonium ylides with aldehydes. A novel reaction mode of the heaviest group V element ylide.
T Ogawa, T Murafuji, H Suzuki
Index: Ogawa, Takuji; Murafuji, Toshihiro; Suzuki, Hitomi Chemistry Letters, 1988 , # 5 p. 849 - 852
Full Text: HTML
Citation Number: 26
Abstract
Stabilized bismuthonium ylides, triphenylbismuthonio-4, 4-dimethyl-2, 6-dioxocyclohexane- 1-ide and triphenylbismuthonio-4, 4-dimethyl-2, 6-dioxo-3, 5-dioxan-1-ide, react with aldehydes to afford three types of products; tetraacylcyclopropanes, dihydrofurans, and α, β- unsaturated carbonyl compounds, the relative importance of these depending greatly on the ylides, aldehydes, and reaction conditions employed.
Related Articles:
[Kumar, Dhruva; Suresh; Sandhu, Jagir S. Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2013 , vol. 52, # 8 p. 1157 - 1160]
[Wang, Qi-Fang; Hui, Li; Hou, Hong; Yan, Chao-Guo Journal of Combinatorial Chemistry, 2010 , vol. 12, # 2 p. 260 - 265]
[Wang, Qi-Fang; Hui, Li; Hou, Hong; Yan, Chao-Guo Journal of Combinatorial Chemistry, 2010 , vol. 12, # 2 p. 260 - 265]
[Wang, Qi-Fang; Hui, Li; Hou, Hong; Yan, Chao-Guo Journal of Combinatorial Chemistry, 2010 , vol. 12, # 2 p. 260 - 265]
[Wang, Qi-Fang; Hui, Li; Hou, Hong; Yan, Chao-Guo Journal of Combinatorial Chemistry, 2010 , vol. 12, # 2 p. 260 - 265]