Iridium (i)-catalyzed vinylic C–H borylation of 1-cycloalkenecarboxylates with bis (pinacolato) diboron

I Sasaki, H Doi, T Hashimoto, T Kikuchi, H Ito…

Index: Sasaki, Ikuo; Doi, Hana; Hashimoto, Toshiya; Kikuchi, Takao; Ito, Hajime; Ishiyama, Tatsuo Chemical Communications, 2013 , vol. 49, # 68 p. 7546 - 7548

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Citation Number: 9

Abstract

Very recently, we reported the regioselective direct ortho borylation of various benzoates or aryl ketones using the complex [Ir(OMe)(cod)] 2 /P[3,5-(CF 3 ) 2 C 6 H 3 ] 3 or AsPh 3 . 7 At the same time, several groups, including Sawamura's, 8 Lassaletta's, 9 and Hartwig's groups, 10 also reported similar borylation of functionalized arenes. The regioselectivity of these reactions is probably driven by the interaction between the coordinating O and N atoms in the directing group ...

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