Carbonylmetallates and carbanions in aromatic and vinylic nucleophilic substitution

…, GA Artamkina, AY Mil'Chenko…

Index: Beletskaya; Artamkina; Mil'Chenko; Sazonov; Shtern Journal of Physical Organic Chemistry, 1996 , vol. 9, # 6 p. 319 - 328

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Citation Number: 22

Abstract

Abstract The kinetic data on the reactions of carbonylmetallates M′ M (CO) n L m, with polyfluorinated arenes and alkenes are reported. The behaviour of these transition metal anionic nucleophiles is compared with the reactivity of both carbanions, and non-transition metal centred anions.