Cross-metathesis reaction of vinyl sulfones and sulfoxides
A Michrowska, M Bieniek, M Kim, R Klajn, K Grela
Index: Michrowska, Anna; Bieniek, Michal; Kim, Mikhail; Klajn, Rafal; Grela, Karol Tetrahedron, 2003 , vol. 59, # 25 p. 4525 - 4531
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Citation Number: 47
Abstract
Cross-metathesis reactions of α, β-unsaturated sulfones and sulfoxides in the presence of molybdenum and ruthenium pre-catalysts were tested. A selective metahesis reaction was achieved between functionalized terminal olefins and vinyl sulfones by using the 'second generation'ruthenium catalysts 1c–h while the highly active Schrock catalyst 1b was found to be functional group incompatible with vinyl sulfones. The cross-metathesis products were ...
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