Total Syntheses of Eudistomins Y1–Y7 by an Efficient One??Pot Process of Tandem Benzylic Oxidation and Aromatization of 1??Benzyl??3, 4??dihydro?螃漫?Carbolines

…, J Dong, Q Zhang, B Zheng, TZ Meng…

Index: Trieu, Tien Ha; Dong, Jing; Zhang, Qiang; Zheng, Bo; Meng, Tian-Zhuo; Lu, Xia; Shi, Xiao-Xin European Journal of Organic Chemistry, 2013 , # 16 p. 3271 - 3277

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Citation Number: 6

Abstract

Abstract The first total synthesis of eudistomin Y 7 (7) and total syntheses of eudistomins Y 1– Y 6 (1–6) are described. An efficient room-temperature conversion of 1-benzyl-3, 4-dihydro- β-carbolines (11) into 1-benzoyl-β-carbolines (14) by a one-pot process of tandem benzylic oxidation and aromatization as the key step of these total syntheses was also studied in detail.

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