Journal of the American Chemical Society

Kinetics of a 1, 3-CH carbene insertion reaction: tert-butylchlorocarbene

RA Moss, GJ Ho

Index: Moss, Robert A.; Ho, Guo-Jie Journal of the American Chemical Society, 1990 , vol. 112, # 14 p. 5642 - 5644

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Citation Number: 37

Abstract

5 6-376 nm, k-2.4 X IO9 M-'sI) a nd that a (linear) correlation of the observed pseudo-first- order rate constants for the growth of 2 vs [pyr], extrapolated to [pyr]= 0, gave ko-1.1 X IO7 sl, a rate constant that represented the sum of all first-order and pseudo-first-order decay channels of 1 in the absence of~ yr.~ These competitive pathways included intermolecular reactions of 1 with its diazirine precursor (3) 5 and with solvent, as well as intramolecular 1 ...

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