Journal of Organometallic Chemistry

Syntheses and ultraviolet spectra of N-organosilyl ketimines

LH Chan, EG Roschow

Index: Chan,L.; Rochow,E.G. Journal of Organometallic Chemistry, 1967 , vol. 9, p. 231 - 250

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Citation Number: 64

Abstract

Abstract Twenty eight silyl ketimines and several germanium and tin analogs have been prepared by the action of sodium bis (trimethylsilyl) amide on non-enolizable ketones or the reaction of lithium derivatives of ketimines with organosilicon chlorides. Their electronic spectra, the n→ π* transition in particular, have been investigated to the d*-p* interaction between the empty d orbitals of silicon and the π system of the C N bond. The spectral ...