Mannich reactions of 2-fluoro-2, 2-dinitroethanol

V Grakauskas, K Baum

Index: Grakauskas,V.; Baum,K. Journal of Organic Chemistry, 1971 , vol. 36, p. 2599 - 2602

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Citation Number: 8

Abstract

Izu. Akad. Nauk SSSR, Ser. Khim., 383 (1970). to NH~ C (CH~ OAC)~.~ Ammonia yielded 2- fluoro-2, 2-dinitr~ ethylamine~ or bis (2-fluoro-2, 2-dinitroethyl)-ami~~ e,~,~ depending on the reaction conditions, whereas NH& (CH20Ac) a gave the 1: 1 condensation product. The present study explores the scope of the Mannich reaction of 2-fluoro-2, 2-dinitroethanol. The reactions of a variety of primary and secondary amines with 2-fluoro-2, 2-dinitroethanol ...