Organic fluorine compounds. Part XL. Further reactions of diethyl fluoro-oxaloacetate with aldehydes

ED Bergmann, I Shahak, E Sal'i…

Index: Bergmann,E.D. et al. Journal of the Chemical Society [Section] C: Organic, 1968 , p. 1232 - 1235

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Citation Number: 3

Abstract

The scope of the synthesis of α-fluoro-unsaturated acids from aliphatic and aromatic aldehydes and diethyl fluoro-oxaloacetate has been studied. α-Formyl derivatives of ketones and esters react in their aldehydic forms. 2-Fluoro-3-(2-thienyl) acrylic acid could be nitrated, probably in the 5-position of the thiophen ring. 2-Fluoro-3-(1-naphthyl) acrylic acid cyclized to 2-fluoro-4, 5-benzinden-1-one (VIII).

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