Aluminum alcoholate of hemiacetal. Intermediate in the Tishchenko reaction

T Saegusa, T Ueshima, K Kauchi…

Index: Saegusa,T. et al. Journal of Organic Chemistry, 1968 , vol. 33, # 9 p. 3657 - 3658

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Citation Number: 8

Abstract

3658 NOTES The Journal of Organic Chemistry electron-withdrawing effect at 30". The Meerwein-Ponndorf-Verley reduction is another possible reaction of aluminum alcoholate with a carbonyl compound. The possibility of this reaction, however, was eliminated because of the absence of a hydrogen atom on the a-carbon atom in the t-butoxy group. The structure of I1 was confirmed by elemental analysis and by the products of acid hydrolysis and of ...