Convenient synthesis of thiazyl hexafluoroarsenate (V),[SN]+[AsF6]-, and small quantities of thiazyl fluoride, NSF

A Apblett, AJ Banister, D Biron, AG Kendrick…

Index: Apblett, Allen; Banister, Arthur J.; Biron, David; Kendrick, Aidan G.; Passmore, Jack; et al. Inorganic Chemistry, 1986 , vol. 25, p. 4451 - 4452

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Citation Number: 21

Abstract

The simplest, stable sulfur-nitrogen species is the cation [SN]'. This has been known to have considerable potential as a building block in the synthesis of a wide range of sulfur-nitrogen- containing compound^.^-^[SN]+[MF,]-(M= As, Sb) were first prepared by the reaction of NSF and MF, according to eq 1., It has also