Nature and Kinetic Analysis of Carbon− Carbon Bond Fragmentation Reactions of Cation Radicals Derived from SET-Oxidation of Lignin Model Compounds

…, S Gnanakaran, P Langan…

Index: Brunow, Goesta; Lundquist, Knut Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1984 , vol. 38, # 4 p. 323 - 326

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Citation Number: 42

Abstract

... Chem. ... of diastereomeric dimeric lignin β-1 (4) and β-O-4 (8) model compounds (Figure 4). Kinetic analyses of these reactions show that significant ... the diastereomers of 8. In addition, reactions of 8E and 8T in the presence of O 2 take place with similar chemical efficiencies but ...

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