Migratory aptitudes of simple alkyl groups in the anionotropic rearrangement of quaternary chloromethyl borate species: A combined experimental and theoretical …

A Bottoni, M Lombardo, A Neri…

Index: Journal of Organic Chemistry, , vol. 68, # 9 p. 3397 - 3405

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Citation Number: 20

Abstract

... The Journal of Organic Chemistry. ... J. Org. Chem. ... Introduction. The anionotropic rearrangement of a tetrasubstituted borate ion, via boron-to-carbon 1,2-shift, is at the basis of the most useful applications of organoboranes in organic synthesis. ...