Total synthesis of kaempferol and methylated kaempferol derivatives
YJ Lee, TD Wu
Index: Lee, Yean-Jang; Wu, Tsao-Dong Journal of the Chinese Chemical Society, 2001 , vol. 48, # 2 p. 201 - 206
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Citation Number: 34
Abstract
Abstract Kaempferol (1), a natural product from various plants, was synthesized in which the longest linear sequence is only seven steps in over all yields of 47% from commercially avail able 1, 3, 5-trimethoxybenzene (10). The methylated kaempferols 2–5 were also pre pared by use of this concise synthetic methodology. The key transformations in this synthesis involved the I 2 oxidative-promoting-cyclization and DDO oxidative hydroxylation. Several ...
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