Tetrahedron letters

Intermolecular reaction of nitroxide radicals with biradical intermediates generated from aromatic enediynes

JW Grissom, GU Gunawardena

Index: Grissom, Janet Wisniewski; Gunawardena, Gamini U. Tetrahedron Letters, 1995 , vol. 36, # 28 p. 4951 - 4954

Full Text: HTML

Citation Number: 29

Abstract

1, 4-Dehydronaphthalene biradicals generated by thermolysis of aromatic enediynes can be trapped with the nitroxide radical TEMPO. The isolated products, however, are not the direct trapping products but 1, 4-naphthoquinones resulting from the homolysis of N O bonds of trapping products.

Related Articles:

Chromium (VI) oxide catalyzed oxidation of sulfides to sulfones with periodic acid

[Yamazaki, Shigekazu Tetrahedron Letters, 2001 , vol. 42, # 19 p. 3355 - 3357]

Diels-Alder reactions using supercritical water as an aqueous solvent medium

[Korzenski, Michael B.; Kolis, Joseph W. Tetrahedron Letters, 1997 , vol. 38, # 32 p. 5611 - 5614]

Synthesis and asymmetric Diels-Alder reactions of (S)-2-p-tolylsulfinyl-1, 4-benzoquinone

[Carreno, M. Carmen; Ruano, Jose L. Garcia; Urbano, Antonio Tetrahedron Letters, 1989 , vol. 30, # 30 p. 4003 - 4006]

More Articles...