New latent organotin catalysts: preparation and mechanism of the thermal decomposition of bis [2-(acyloxy) alkyl] diorganotins

B Jousseaume, V Gouron, B Maillard, M Pereyre…

Index: Jousseaume, Bernard; Gouron, Veronique; Maillard, Bernard; Pereyre, Michel; Frances, Jean-Marc Organometallics, 1990 , vol. 9, p. 1330 - 1331

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Citation Number: 10

Abstract

Summary: New organotin compounds, bis (2-(acyloxy)-alkyl) diorganotins, can be thermally decomposed into diorganotin dicarboxylates. The substituent effects on the reaction parameters are studied, and a possible mechanism for the decomposition is proposed. These tetraorganotins can be regarded as latent catalysts for silicone curing and polyurethane preparation.