Mechanistic aspects of the silver (I)-promoted rearrangement of cyclopropene derivatives

A Padwa, TJ Blacklock, R Loza

Index: Padwa, Albert; Blacklock, Thomas J.; Loza, Roman Journal of Organic Chemistry, 1982 , vol. 47, # 19 p. 3712 - 3721

Full Text: HTML

Citation Number: 47

Abstract

The silver ion promoted isomerizations of several substituted cyclopropenes have been studied. The results of these studies have been compared to the rearrangements encountered on thermolysis and photolysis. Treatment of 1, 3-diphenyl-2-methyl-3- benzylcyclopropene with silver ion afforded l-phenyl-2-methyl-3-benzylindene as the exclusive product. In contrast, photolysis of this system gave rise to the isomeric l-methyl-2 ...

Related Articles:

Photosensitized electron-transfer-induced reactions of some cyclopropene derivatives

[Padwa, Albert; Chou, Chuen S.; Rieker, William F. Journal of Organic Chemistry, 1980 , vol. 45, # 23 p. 4555 - 4564]

Photosensitized electron-transfer-induced reactions of some cyclopropene derivatives

[Padwa, Albert; Chou, Chuen S.; Rieker, William F. Journal of Organic Chemistry, 1980 , vol. 45, # 23 p. 4555 - 4564]

Photochemical transformations of small ring compounds. 112. Photochemistry of cyclopropene derivatives. Formation and intramolecular trapping reactions of …

[Padwa, Albert; Blacklock, Thomas J.; Loza, Roman; Polniaszek, Richard Journal of Organic Chemistry, 1980 , vol. 45, # 11 p. 2181 - 2189]

Photosensitized electron-transfer-induced reactions of some cyclopropene derivatives

[Padwa, Albert; Chou, Chuen S.; Rieker, William F. Journal of Organic Chemistry, 1980 , vol. 45, # 23 p. 4555 - 4564]

Photochemical transformations of small ring compounds. 95. The problem of regioselectivity in the photochemical ring-opening reaction of 3-phenyl-and 3-vinyl- …

[Padwa,A. et al. Journal of Organic Chemistry, 1978 , vol. 43, # 8 p. 1481 - 1492]

More Articles...