Free-radical reactions of organophosphorus compounds. 9. The question of memory effects in the alkoxy-radical oxidations of cyclic trivalent phosphorus derivatives

A Nakanishi, K Nishikida…

Index: Nakanishi,A. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 6398 - 6402

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Citation Number: 8

Abstract

Abstract: Alkoxy-radical oxidations of a series of five-and six-membered ring phosphites and several five-membered ring phosphorodiamidites (1, 3, 2-diazaphospholanes) were studied. Determinations of product oxide ratios were made in reaction systems designed to generate a potentially common phosphoranyl radical intermediate by two different pathways. Both product studies (31P or GLC) and product radical ratio determinations (ESR) were carried ...