Amination of m-dialkylbenzenes with trichloramine-aluminum chloride

P Kovacic, KW Field, PD Roskos…

Index: Kovacic,P. et al. Journal of Organic Chemistry, 1967 , vol. 32, p. 585 - 588

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Citation Number: 5

Abstract

A variety of 3, 5-dialkylanilines has been prepared by a convenient one-step procedure involving amination of m-dialkylbenzenes with trichloramine-aluminum chloride. The method proves to be satisfactory even when the m-dialkylbenzene is contaminated with the other isomers. Preparation of meta-enriched dialkylbenzene substrates is described. A a- substitution (addition-elimination) mechanism is used to rationalize the observed ...

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