The Journal of Organic Chemistry

Silicon Heterocyclic Compounds. I. Synthesis of the 3-Sila-1-heterocyclohexanes1

RJ Fessenden, MD Coon

Index: Fessenden,R.J.; Coon,M.D. Journal of Organic Chemistry, 1964 , vol. 29, p. 1607 - 1610

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Citation Number: 23

Abstract

Z is 0 (5), Sic12 (7), S (8), and n-C4H9N. HBr (9) have been synthesized. The 6-alkyl derivatives (R= CHJ, C2Hs, and CIH7) were prepared in the case where Z= 0. Compound 5 (R= H) was prepared by the following sequence, starting with allyl alcohol (1). Reaction of 1 and [(CH3) sSi2] NH gave CHz= CHCH (R) OSi (CHa) a (2). Condensation of 2 with (CH&SiH (CHZCl) using platinum on carbon aa catalyst gave CICHzSi (CH3) &HZCH2- ...