Electron impact studies. CXV. Release of kinetic energy during negative ion decompositions. CO bond cleavage reactions

G Klass, JH Bowie

Index: Klass,G.; Bowie,J.H. Australian Journal of Chemistry, 1977 , vol. 30, p. 1249 - 1254

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Citation Number: 4

Abstract

Abstract Kinetic energy release values T (50%) for the collision-induced formation of the p- nitrobenzoate and p-nitrophenoxide anions from the molecular anions of pO 2 NC 6 H 4 COOC 6 H 4 Rp and pO 2 NC 6 H 4-OC 6 H 4 Rp respectively are small and relatively insensitive to the nature of the substituent RT (50%) values for the elimination of R?(R= alkyl) from O 2 NC 6 H 4 OR molecular anions range from 0.4 to 0.01 eV, and are ...