A novel procedure for the synthesis of aziridines: application of Simmons–Smith reagents to aziridination

VK Aggarwal, RA Stenson, RVH Jones, R Fieldhouse…

Index: Aggarwal, Varinder K; Stenson, Rachel A.; Jones, Ray V.H.; Fieldhouse, Robin; Blacker, John Tetrahedron Letters, 2001 , vol. 42, # 8 p. 1587 - 1589

Full Text: HTML

Citation Number: 37

Abstract

Aziridines are versatile synthetic intermediates that can undergo regio- and stereoselective ring-opening reactions with both heteroatomic and carbon nucleophiles. 1., , and Non-racemic, terminal aziridines are an important class of these saturated heterocycles and have been prepared from α-amino acids, 2., , , and epoxides, 3., and carbohydrates, 4 or by transformations of CC 5., , , and and CN bonds. 6., , and We have described a novel method for the ...

Related Articles:

Stereoselectivity and Substrate Specificity in the Kinetic Resolution of Methyl-Substituted 1-Oxaspiro [2.5] octanes by Rhodotorula g lutinis Epoxide Hydrolase

[Toda, Fumio; Imai, Nobuhiro Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 19 p. 2673 - 2674]

The asymmetric synthesis of terminal aziridines by methylene transfer from sulfonium ylides to imines

[Kavanagh, Sarah A.; Piccinini, Alessandro; Connon, Stephen J. Organic and Biomolecular Chemistry, 2013 , vol. 11, # 21 p. 3535 - 3540]

The (Porphyrin) ruthenium??Catalyzed Aziridination of Olefins Using Aryl Azides as Nitrogen Sources

[Fantauzzi, Simone; Gallo, Emma; Caselli, Alessandro; Piangiolino, Cristiana; Ragaini, Fabio; Cenini, Sergio European Journal of Organic Chemistry, 2007 , # 36 p. 6053 - 6059]

More Articles...