Synthèse et thermolyse de vinyl-2 aziridines N-non substituées

…, Y Gelas-Mialhe, R Vessiere

Index: Attia, Mohamed El Mekki; Gelas-Mialhe, Yvonne; Vessiere, Roger Canadian Journal of Chemistry, 1983 , vol. 61, p. 2126 - 2132

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Citation Number: 10

Abstract

N-unsubstituted 2-vinylaziridines are prepared from N-unsubstituted 2-acylaziridines and phosphoranes. Their stereochemistry is established from a study of their nmr spectra. Thermal isomerization of these compounds gives imines by a reaction involving hetcrolytic cleavage of the carbon-carbon bond of the ring and migration of hydrogen initially bound to nitrogen.