Liquid Triarylamines: The Scope and Limitations of Piers–Rubinsztajn Conditions for Obtaining Triarylamine–Siloxane Hybrid Materials

BA Kamino, B Mills, C Reali, MJ Gretton…

Index: Kamino, Brett A.; Mills, Bridget; Reali, Christopher; Gretton, Michael J.; Brook, Michael A.; Bender, Timothy P. Journal of Organic Chemistry, 2012 , vol. 77, # 4 p. 1663 - 1674

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Citation Number: 27

Abstract

New liquid triarylamine–siloxane hybrid materials are produced using the Piers–Rubinsztajn reaction. Under mild conditions, liquid analogues of conventional and commonly crystalline triarylamines are easily synthesized from readily available or accessible intermediates. Using a diverse selection of triarylamines, we explored the effects of siloxane group and substitution pattern on the physical properties of these materials, and we have ...

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