International Journal of Chemical Kinetics

Kinetic evidence for the occurrence of kinetically detectable intermediates in the cleavage of N??ethoxycarbonylphthalimide under N??methylhydroxylamine buffers

MN Khan

Index: Khan, N. Niyaz International Journal of Chemical Kinetics, 2002 , vol. 34, # 2 p. 95 - 103

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Citation Number: 3

Abstract

Abstract The kinetics of the aqueous cleavage of N-ethoxycarbonylphthalimide (NCPH) in CH 3 NHOH buffers of different pH reveals that the cleavage follows the general irreversible consecutive reaction path NCPH equation image ENMBC equation image A equation image B, where ENMBC, A, and B represent ethyl N-[o-(N-methyl-N-hydroxycarbamoyl) benzoyl] carbamate, N-hydroxyl group cyclized product of ENMBC, and o-(N-methyl-N- ...