Formation of carboxylate complexes from the reactions of carbon dioxide with ethylene complexes of molybdenum and tungsten. X-ray and neutron diffraction studies

R Alvarez, E Carmona, A Galindo, E Gutierrez…

Index: Alvarez, Rafael; Carmona, Ernesto; Galindo, Agustin; Gutierrez, Enrique; Marin, Jose M.; et al. Organometallics, 1989 , vol. 8, p. 2430 - 2439

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Citation Number: 51

Abstract

Conclusions The preparation of several new diplatinum complexes containing p- phenylethenylidene ligands is reported. X-ray structural determinations of three of these compounds confirm unambiguously the molecular structures of two new classes of diplatinum halide complexes. Theoretical calculations indicate that the electronic structure of these molecules might be similar to that found previously for Pt2 (POP) 44-. Study of the ...