Journal of the American Chemical Society

Carbanions from deprotonation of. alpha.-(phenylthio) alkaneboronic esters

DS Matteson, K Arne

Index: Matteson,D.S.; Arne,K. Journal of the American Chemical Society, 1978 , vol. 100, p. 1325 - 1326

Full Text: HTML

Citation Number: 35

Abstract

Sir: The deprotonation of gem-diboronic esters' and the chemistry of (phenylthio) methylIithiu~ n~~~ suggested the preparation of pinacol (pheny1thio) methaneboronate (la) and its deprotonation by lithium diisopropylamide (LDA) to the carbanion 2a. This route to boron substituted carbanions is significantly easier and cheaper than those found previousand derivatives of 2a show promise of versatile and useful synthetic chemistry. ...

Related Articles:

Metal catalysed hydroboration of vinyl sulfides, sulfoxides, sulfones, and sulfonates

[Webb, Jonathan D.; Harrison, Daniel J.; Norman, David W.; Blacquiere, Johanna M.; Vogels, Christopher M.; Decken, Andreas; Bates, Craig G.; Venkataraman; Baker, R. Thomas; Westcott, Stephen A. Journal of Molecular Catalysis A: Chemical, 2007 , vol. 275, # 1-2 p. 91 - 100]

Carbanions from. alpha.-phenylthio boronic esters as synthetic intermediates

[Matteson, Donald S.; Arne, Karl H. Organometallics, 1982 , vol. 1, p. 280 - 288]

Carbanions from. alpha.-phenylthio boronic esters as synthetic intermediates

[Matteson, Donald S.; Arne, Karl H. Organometallics, 1982 , vol. 1, p. 280 - 288]

More Articles...