Direct coupling of alcohols with alkenylsilanes catalyzed by indium trichloride or bismuth tribromide

Y Nishimoto, M Kajioka, T Saito, M Yasuda…

Index: Nishimoto, Yoshihiro; Kajioka, Masayuki; Saito, Takahiro; Yasuda, Makoto; Baba, Akio Chemical Communications, 2008 , # 47 p. 6396 - 6398

Full Text: HTML

Citation Number: 15

Abstract

Although a carbon–carbon bond formation using an alcohol as a coupling partner might be fascinating in organic chemistry, the system is much more difficult than that using other partners such as organic halides because of the poor leaving ability of the hydroxy group. The use of alcohols, which are plentiful and inexpensive compounds, can have advantages over the use of the corresponding organic halides, and the establishment of this reaction system has ...

Related Articles:

N-Alkenyl nitrone dipolar cycloaddition routes to piperidines and indolizidines. Part 8. The scope of tandem reactions involving hydroxylamine-alkyne cyclisations

[Davison, Edwin C.; Forbes, Ian T.; Holmes, Andrew B.; Warner, Jacqueline A. Tetrahedron, 1996 , vol. 52, # 35 p. 11601 - 11624]

Pd-catalyzed cycloisomerization to 1, 2-dialkylidenecycloalkanes. 1

[Trost, Barry M.; Tanoury, Gerald J.; Lautens, Mark; Chan, Chuen; MacPherson, David T. Journal of the American Chemical Society, 1994 , vol. 116, # 10 p. 4255 - 4267]

Polyacetylenverbindungen, 203. Zur Biogenese des Matricariaesters

[Bohlmann,F.; Burkhardt,T. Chemische Berichte, 1972 , vol. 105, p. 521 - 528]

More Articles...