The Journal of Organic Chemistry

Reaction of 4-(iodomethyl) azetidin-2-ones with tetracarbonylferrate (II)

G Georg, T Durst

Index: Georg, Gunda; Durst, Tony Journal of Organic Chemistry, 1983 , vol. 48, # 12 p. 2092 - 2095

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Citation Number: 12

Abstract

1.'The tetracarbonyl ferrate dianion, an excellent nucleophile, is fiit readed with an alkyl halide to form the acyliron intermediate 6, the result of initial formation of a carbon-iron bond followed by CO insertion. The intermediate 6 can also be prepared directly from 1 upon reaction with acid halides. It is less reactive than 1 and is alkylated only by the very reactice primary alkyl iodidea The reagent 1 was shown to react cleanly with primary bromides and ...

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