Organometallics

Direct Observation of C–H Cyclopalladation at Tertiary Positions Enabled by an Exo-Directing Group

Z Ren, G Dong

Index: Saget, Tanguy; Perez, David; Cramer, Nicolai Organic Letters, 2013 , vol. 15, # 6 p. 1354 - 1357

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Citation Number: 2

Abstract

... However, complex 8 exhibits low solubility in most organic solvents, which hampered NMR characterization and further reactivity ... figure Scheme 2. C–H Cyclopalladation at Tertiary sp 3 Positions with Substrate 6. ... Pd–C(2), 2.041; Pd–O(2), 2.084; Pd–N(1), 2.021; Pd–P(1), 2.264. ...