Tetrahedron letters

Reinvestigation of the reaction between sodium diethyl phosphite and diethyl phosphorochloridate. Evidence for a SET process in the formation of a direct P (IV) P ( …

RW Kinas, A Okruszek, WJ Stec

Index: Kinas, Ryszard W; Okruszek, Andrzej; Stec, Wojciech J Tetrahedron Letters, 2002 , vol. 43, # 44 p. 7875 - 7879

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Citation Number: 4

Abstract

Alkali metal salts of diethyl phosphites act as nucleophiles or electron donors in reactions with diethyl phosphorochloridate. Evidence is provided that formation of the direct P (IV) P (IV) bond proceeds via a single electron transfer process (SET) from phosphite anion to phosphorochloridate.

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