Journal of the American Chemical Society

Photochemical electron-transfer reactions of 1, 1-diarylethylenes

SL Mattes, S Farid

Index: Mattes,S.L.; Farid,S. Journal of the American Chemical Society, 1986 , vol. 108, p. 7356

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Citation Number: 154

Abstract

Abstract: The dimerizations, nucleophilic additions, and oxygenation reactions of 1, l- diarylethylenes (l), induced by photoexcited cyanoanthracenes, have been investigated. 1, l- Diphenylethylene (la) yields 2+ 2 and 2+ 4 cyclodimers and one dehydrodimer, whereas 1, l- dianisylethylene (lb) gives two dehydrodimers, and 1, l-bis (4-(dimethylamino) phenyl) ethylene (IC) forms no dimers. Formation of the dehydrodimers is accompanied by ...

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