Studies in stereochemistry. XL. Unusual magnitudes of optical rotations of imines of neopentylamine-1-d and ethylamine-1-d

W Meister, RD Guthrie, JL Maxwell…

Index: Meister,W. et al. Journal of the American Chemical Society, 1969 , vol. 91, p. 4452 - 4458

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Citation Number: 11

Abstract

Abstract: The origins of the high magnitudes of rotations of imines of optically pure (+)-(R)- neopentylamine-1-d and of optically active ethylamine-1-d have been investigated. The optical rotatory dispersion curves and ultraviolet spectra are reported of (+)-(R)-N- (isopropy1idene) neopentylamine-1-d (IIb),(+)-(A)-N-(benzhydry1idene)-neopentylamine-1- d (IIc),(+)-(R)-N-(at-butylbenzy1idene) neopentylamine-1-d (IId),(+)-(R)-N-(a-methylbenzyl ...