The Journal of Organic Chemistry

Palladium-catalyzed reactions of acyl chlorides with (1-alkynyl) tributylstannanes. A convenient synthesis for 1-alkynyl ketones

MW Logue, K Teng

Index: Logue, Marshall W.; Teng, Kelly Journal of Organic Chemistry, 1982 , vol. 47, # 13 p. 2549 - 2553

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Citation Number: 179

Abstract

As a class, a,@-acetylenic carbonyl compounds are extremely versatile substrates for further synthetic elaboration. Numerous syntheses involving a,@-acetylenic carbonyl compounds have been reported? and a significant number of them involve the synthesis of heterocyclic compounds. The facility with which a,@-acetylenic carbonyl compounds undergo nucleophilic additions and cyclizati~ ns~~~~~~~ makes them very desirable intermediates ...

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