The Journal of Organic Chemistry

Oxidations with Oxygen Difluoride. II. Addition to Unsaturated Carbon

RF Merritt, JK Ruff

Index: Merritt,R.F.; Ruff,J.K. Journal of Organic Chemistry, 1965 , vol. 30, p. 328 - 331

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Citation Number: 18

Abstract

Following the initial preparation of oxygen difluoride (OF,) by Lebeau and Damiens' in 1927, the investigation of the chemistry of this powerful oxidant was confined to various inorganic systems. However, recent work3 has shown that OF, oxidations of organic substrates can be controlled in the case of primary aliphatic amines. The facile amine oxidationJ3 which was rapid at-78', suggested extension of similar

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