Synlett

Iron-Catalyzed Benzylation Reaction of Arenes with Benzyl Thiocyanates

…, DY Zhao, JH Li, XG Zhang, CL Deng, RY Tang

Index: Guo, Xiao-Kang; Zhao, Dong-Yun; Li, Jin-Heng; Zhang, Xing-Guo; Deng, Chen-Liang; Tang, Ri-Yuan Synlett, 2012 , # 4 p. 627 - 631

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Citation Number: 6

Abstract

Abstract A novel, regioselective protocol for the synthesis of diphenylmethane derivatives has been developed by using iron-catalyzed Friedel-Crafts reaction of arenes with benzyl thiocyanates. In the presence of FeBr 3, a variety of benzyl thiocyanates underwent the reaction with arenes to selectively afford the corresponding diarylmethane derivatives in moderate to high yields.

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