Tetrahedron

Chromium pillared clay catalysed allylic oxidation and oxidative deprotection of allyl ethers and amines: a simple and convenient procedure

BM Choudary, AD Prasad, V Swapna, VLK Valli…

Index: Choudary, Boyapati M.; Prasad, Annavajhula Durga; Swapna, Vinukonda; Valli, Velaga L. K.; Bhuma, Vedantam Tetrahedron, 1992 , vol. 48, # 5 p. 953 - 962

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Citation Number: 36

Abstract

An efficient method for allylic oxidation of cyclic and acyclic alkenes to the corresponding α, β-unsaturated carbonyl compounds in good yields was described using catalytic amounts of chromia-pillared montmorillonite and equimolar quantities of tert-butyl hydroperoxide. This is also a convenient method for selective oxidative deprotection of allyl ethers and amines using same system. Incidentally this is the first heterogeneous system for the allylic ...

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