Tetrahedron

Na 4 H 3 [SiW 9 Al 3 (H 2 O) 3 O 37]· 12H 2 O/H 2 O: a new system for selective oxidation of alcohols with H 2 O 2 as oxidant

J Wang, L Yan, G Qian, S Li, K Yang, H Liu, X Wang

Index: Wang, Jianmin; Yan, Liang; Qian, Guang; Li, Shunqing; Yang, Keli; Liu, Haitao; Wang, Xiaolai Tetrahedron, 2007 , vol. 63, # 8 p. 1826 - 1832

Full Text: HTML

Citation Number: 19

Abstract

This work describes a catalytic system consisting of both Na4H3 [SiW9Al3 (H2O) 3O37]· 12H2O (SiW9Al3) and water as solvents (a small quantity of organic solvents were used as co-solvent for a few substrates) that can be good for selective oxidation of alcohols to ketones (aldehydes) using 30% H2O2 without any phase-transfer catalyst under mild reaction conditions. The catalyst system allows easy product/catalyst separation. Under ...

Related Articles:

Catalytic ring opening of acetylcyclopropane by water and alcohols under the action of copper or palladium salts

[Dzhemilev; Khusnutdinov; Atnabaeva; Muslimov; Parfenova; Tomilov Russian Chemical Bulletin, 2001 , vol. 50, # 7 p. 1242 - 1247]

Quantitative structure-activity relationships for the enantioselectivity of oxirane ring-opening catalyzed by epoxide hydrolases

[Steinreiber, Andreas; Osprian, Ingrid; Mayer, Sandra F.; Orru, Romano V. A.; Faber, Kurt European Journal of Organic Chemistry, 2000 , # 22 p. 3703 - 3711]

Selective oxidation of diols by H 2 O 2/TS-1 system and by DMDO

[Bovicelli, Paolo; Lupattelli, Paolo; Sanetti, Anna; Mincione, Enrico Tetrahedron Letters, 1994 , vol. 35, # 45 p. 8477 - 8480]

Regioselectivity in the semiconductor-mediated photooxidation of 1, 4-pentanediol

[Fox, Marye Anne; Ogawa, Haruo; Pichat, Pierre Journal of Organic Chemistry, 1989 , vol. 54, # 16 p. 3847 - 3852]

More Articles...