European Journal of Organic Chemistry

Stereoselective Olefination of N??Sulfonyl Imines with Stabilized Phosphonium Ylides for the Synthesis of Electron??Deficient Alkenes

F Fang, Y Li, SK Tian

Index: Fang, Fan; Li, Yuan; Tian, Shi-Kai European Journal of Organic Chemistry, 2011 , # 6 p. 1084 - 1091

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Citation Number: 21

Abstract

Abstract An unprecedented protocol has been developed for thestereoselective synthesis of structurally diverse electron-deficient alkenes in moderate to excellent yields from readily accessible N-sulfonyl imines and stabilized phosphonium ylides. Significantly, the olefination reaction of N-sulfonylimines with nitrile-stabilized phosphonium ylides affords an array of α, β-unsaturated nitriles with high Z selectivity, and the reactions with ester-, ...

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