Journal of organometallic chemistry

Allylchlorotins as allylating agents of acyl chlorides

A Gambaro, V Peruzzo, D Marton

Index: Gambaro, Alessandro; Peruzzo, Valerio; Marton, Daniele Journal of Organometallic Chemistry, 1983 , vol. 258, # 3 p. 291 - 296

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Citation Number: 6

Abstract

Abstract Allylchlorotins of the type R 3-n AllSnCl n (R alkyl or All; All CH 2 CHCH 2 or cis/trans-CH 3 CH CHCH 2, n 1–3) undergo uncatalyzed coupling with acyl chlorides under mild conditions. This reaction as well as the corresponding addition reaction to ketones are much faster when Cl is replaced by NCS group in the organotin derivative.

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