Silanones and silanethiones from the reactions of transient silylenes with oxiranes and thiiranes in solution. The direct detection of diphenylsilanethione.
SS Kostina, WJ Leigh
Index: Khabashesku, V. N.; Kerzina, Z. A.; Baskir, E. G.; Maltsev, A. K.; Nefedov, O. M. Journal of Organometallic Chemistry, 1988 , vol. 347, p. 277 - 294
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Citation Number: 12
Abstract
... Journal of the ... lived transient product exhibiting λ max ≈ 275 nm, which has been assigned to diphenylsilanethione (Ph 2 Si═S) on the basis ... For example, both species typically react rapidly with water and alcohols via net O−H insertion, yet singlet carbenes most commonly do ...
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