Journal of Fluorine Chemistry

Aromatic fluoroderivatives. XCVI. Reactions of polyfluoroaromatic compounds with salts of the fluorochloronium and fluorobromonium

VV Bardin, GG Furin, GG Yakobson

Index: Bardin,V.V.; Furin,G.G. Journal of Fluorine Chemistry, 1983 , vol. 23, p. 67

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Citation Number: 12

Abstract

Abstract Polyfluorinated derivatives of benzene, naphthalene and pyridine react with salts of the difluorochloronium ClF+ 2, difluorobromonium BrF+ 2 and tetrafluorobromonium BrF+ 4 cations to give fluorinated derivatives of 1, 4-cyclohexadiene and 1-aza-1, 3-cyclohexadiene respectively. In the absence of fluorine anion acceptors, ClF 3, BrF 3 and BrF 5 are less reactive in these reactions than salts of the HalF+ n cations.