Stereoselective Synthesis of Phosphoryl??Substituted Phenols

…, Y Liu, Y Zhou, C Zhao, M Goto, SF Yin…

Index: Xiong, Biquan; Li, Mei; Liu, Yanxi; Zhou, Yongbo; Zhao, Changqiu; Goto, Midori; Yin, Shuang-Feng; Han, Li-Biao Advanced Synthesis and Catalysis, 2014 , vol. 356, # 4 p. 781 - 794

Full Text: HTML

Citation Number: 11

Abstract

Abstract: Copper-catalyzed CÀX activation-phosphorylation of aryls bearing different groups has been achieved using P (O) ÀH compounds as efficient phosphorylation reagents without the assistance of any ligand. Optically active H-phosphinates can also act as good substrates in the reaction, giving the (Sp)-phosphoryl substituted phenolic compounds stereospecifically with retention of configuration at the phosphorus center. Furthermore, it ...

Related Articles:

SYNTHESIS AND SUBSTITUENT EFFECT ON 31P NMR CHEMICAL SHIFT OF ORTHO HYDROXYARYL DIALKYL PHOSPHINE OXIDES

[Li, Shusen; Wang, Guoquan Phosphorus, Sulfur and Silicon and the Related Elements, 1991 , vol. 61, # 12 p. 119 - 129]

Phosphaisocoumarins as a new class of potent inhibitors for pancreatic cholesterol esterase

[Li, Baojian; Zhou, Binhua; Lu, Hailiang; Ma, Lin; Peng, Ai-Yun European Journal of Medicinal Chemistry, 2010 , vol. 45, # 5 p. 1955 - 1963]

More Articles...