Studies on the synthesis of Strychnos indole alkaloids
…, M Salas, M Amat, M Alvarez, I Morgó, B Adrover
Index: Bosch; Salas; Amat; Alvarez; Morgo; Adrover Tetrahedron, 1991 , vol. 47, # 28 p. 5269 - 5276
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Citation Number: 10
Abstract
Tetracycles 3b–d, having the ABCD ring substructure of Strychnos alkaloids and a Nb- (formylmethyl) substituent protected as an oxime or hydrazone derivative, have been prepared by nucleophilic addition of the enolate of indoleacetic ester 1 to pyridinium salts 2b– d followed by acid cyclization. The same one-pot, two-step sequence allowed the preparation of tetracycle 3f, which incorporates an α-methoxyacrylate chain at the ...
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