Synthesis of glycerol carbonate from glycerol and diethyl carbonate over CeO2-CdO catalyst: The role of Ce4+ doped into CdO lattice

Yuanfeng Wu, Xianghai Song, Jiahui Zhang, Shuai Li, Xinghui Yang, Huazheng Wang, Ruiping Wei, Lijing Gao, Jin Zhang, Guomin Xiao

Index: 10.1016/j.jtice.2018.03.023

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Abstract

A series of Ce1-xCdxO mixed oxide catalysts prepared by co-precipitation method were tested for synthesis of glycerol carbonate (GC) from glycerol and diethyl carbonate (DEC). The microstructural and physicochemical properties of the bimetal catalysts were characterized by XRD, SEM, TEM, XPS, CO2-TPD, N2-adsorption, TG-DSC and 1H NMR. The results show that the spherical particles of CdO were uniformly dispersed on the surface of lamellar CeO2. Besides, a noticeable increase was observed in the moderate basic sites concentration, because more oxygen atoms were adsorbed on the bimetal sample surface which was attributed to Ce4+ doped into CdO lattice. The Ce0.7Cd0.3O sample annealed at 500 °C was observed with the highest catalytic activity. 96.84% of glycerol conversion and 100% selectivity to GC were obtained over this catalyst under the optimized conditions (5 wt.% catalyst of glycerol, 90 °C, 180 min, glycerol/DEC molar ratio of 1:3). Besides, it was found that the conversion of glycerol carbonate was synergistically accelerated by the moderate and strong basic sites.