Chemistry–A European Journal

[Pd (Cl) 2 {P (NC5H10)(C6H11) 2} 2]—A Highly Effective and Extremely Versatile Palladium??Based Negishi Catalyst that Efficiently and Reliably Operates at Low …

JL Bolliger, CM Frech

Index: Bolliger, Jeanne L.; Frech, Christian M. Chemistry - A European Journal, 2010 , vol. 16, # 36 p. 11072 - 11081

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Citation Number: 32

Abstract

Abstract [Pd (Cl) 2 {P (NC 5 H 10)(C 6 H 11) 2} 2](1) has been prepared in quantitative yield by reacting commercially available [Pd (cod)(Cl) 2](cod= cyclooctadiene) with readily prepared 1-(dicyclohexylphosphanyl) piperidine in toluene under N 2 within a few minutes at room temperature. Complex 1 has proved to be an excellent Negishi catalyst, capable of quantitatively coupling a wide variety of electronically activated, non-activated, ...

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