Chemische Berichte

Isolation and structure elucidation of the by??product formed in the aminomethylation of α??methylstyrene

P Sohar, J Lazar, G Bernáth

Index: Sohar, Pal; Lazar, Janos; Bernath, Gabor Chemische Berichte, 1985 , vol. 118, # 2 p. 551 - 559

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Citation Number: 4

Abstract

Abstract Aminomethylation of α-methylstyrene (1) leads to 1, 2, 3, 6-tetrahydro-4- phenylpyridine (3) as main product, together with a significant amount of a previously unknown by-product. The N-methyl, O-acetyl-N-methyl, N, O-diacetyl, N-(4-nitrobenzoyl), and (via N [RIGHTWARDS ARROW] O acyl-migration) O-(4-nitrobenzoyl) derivatives of the by-product were synthesized. By aromatization of the heteroring, 4-phenyl-3- ...

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