Inorganic Chemistry

Dehydrohalogenation of adducts of dichloro (pentafluorophenyl) borane with mesidine and p-anisidine: a reinvestigation

JG Morse, WK Glanville

Index: Morse, Joseph G.; Glanville, W. Kent Inorganic Chemistry, 1984 , vol. 23, p. 11 - 13

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Citation Number: 3

Abstract

The pyrolysis of dichloro (pentafluoropheny1) borane with mesidine or p-anisidine, originally reported to yield monomeric boron imides, has been restudied. Rather than boron imides, the reactions give aminoboranes,(aminoboranyl) aminoboranes, or bis (amin0) boranes depending on the duration of pyrolysis. The dimer structure represents an intermediate proposed in the pyrolysis of dichlorophenylborane with aromatic amines to give ...