Long time, low temperature pyrolysis of El-Lajjun oil shale

Jameel S. Aljariri Alhesan, Yi Fei, Marc Marshall, W. Roy Jackson, Ying Qi, Alan L. Chaffee, Peter J. Cassidy

Index: 10.1016/j.jaap.2018.01.017

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Abstract

There is continuing interest in in situ production of oil from oil shale, particularly for deep deposits and for environmental reasons. Such production would involve long-time, low temperature pyrolysis. Accordingly, reactions of El-Lajjun oil shale have been carried out under N2 for 7, 14 and 28 days at temperatures in the range 240-320 °C. The conversion plateaued at 300 °C and above at a value of about 80 wt% dmmf and was the same for 7 and 14 day pyrolysis. The total conversion decreased by 15% as the temperature decreased to 280 °C. The lower conversions at 240 and 260 °C were the same for 14 and 28 days but oil yield increased at the expense of asphaltene for the longer time. Sulfur content of the oil + asphaltene decreased with increasing reaction temperature (240-300 °C) and time (280-300 °C) from 13 wt% to a plateau of about 7 wt%. The characteristics of the oil and oil + asphaltene changed steadily with temperature up to 300 °C, but increasing the temperature further to 320 °C had little effect. The results show that high conversion to products of good characteristics can be obtained for reactions at sufficiently long times at temperatures as low as 300 °C.